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Mallorca's Julio Alvarez celebrates after scoring against Athletic de Bilbao during their Spanish league football match at Ono Stadium in Palma de Mallorca.

Real Madrid spurned the chance to replace Barcelona at the top of the Spanish first division on Sunday firing blanks in a frustrating 0-0 draw against Osasuna in Pamplona.

Barcelona had dropped two points as they lost their 100-percent home record with a 1-1 draw against Villarreal on Saturday but Real could not capitalize and stay two points behind the champions in second.

It was only the second time Real had failed to score in the league this season - the other occasions being a 1-0 loss at Barcelona and a 0-0 draw with Sporting Gijon - and it was a golden opportunity missed.

Real coach Manuel Pellegrini was without Kaka as the Brazilian recovered from a groin injury so Rafael van der Vaart continued as the attacking midfielder behind Cristiano Ronaldo and Gonzalo Higuain.

With Pepe out injured for the season, Argentine Ezequiel Garay joined Raul Albiol in central defence although they were largely untroubled until the 41st minute when a Javad Nekounam header stirred goalkeeper Iker Casillas into action.

Higuain, with five goals in his last three matches, had Real's best chance on 65 minutes but a strong hand from goalkeeper Ricardo Lopez denied the Argentine. Real replaced Higuain with captain Raul in a last throw of the dice but it was to no avail.

While Barcelona have a last 16 Kings Cup match against Sevilla on Tuesday, Real can rest up as they have already been eliminated by minnows Alcorcon.

Osasuna have now held champions Barcelona (1-1) and Real at their Reyno de Navarra stadium and beat them both last season in the final two games of the campaign.

Osasuna needed to beat Real on the final day of last season to stay in the league but this season they are comfortably in mid-table lying 12th.

Real Mallorca are Real's next opponents and they moved above Sevilla into fourth place with a 2-0 win over Athletic Bilbao as they maintained their perfect home record with an eighth successive home victory.

"We are fourth but we face Real Madrid on their patch in the next league game and it will be difficult to get points there," said Mallorca coach Gregorio Manzano.

Julio Alvarez scored the Mallorca opener on 49 minutes to open the scoring before Aritz Aduriz netted his eighth goal of the season against old club Bilbao after 67 minutes.

Mallorca are now in the final Champions League spot and turn their attention to the Kings Cup as they travel to Rayo Vallecano on Wednesday for the first leg of the last 16 tie.

New Almeria coach Juanma Lillo enjoyed a winning start as his side clinched a crucial 1-0 win over relegation rivals Xerez.

Substitute Jose Ortiz Bernal netted an 89th minute winner just three minutes after coming on to gift Lillo a debut win after taking over from axed Mexican Hugo Sanchez.

"I am not bothered about the fact that it was my debut but more that we won the match. That was the most important thing," said Lillo.

"The three points help us make a good leap in the table and see things a bit differently."

Almeria move three points above the relegation zone while basement boys Xerez slide towards relegation lying eight points from safety with just one win all season.

Struggling Malaga were left frustrated as they twice surrendered the lead to be pegged back 2-2 at Sporting Gijon and stay third from bottom.

At the other end of the table Deportivo La Coruna missed the chance to move level on points with fourth-placed Sevilla, who lost 2-1 at Atletico Madrid on Saturday, with a 0-0 draw at Real Zaragoza.